Asked by Carrie
What is the theoretical yield of p-bromotoluene (C7H7Br) from reacting 1.5 grams of toluene (C7H8) with an excess of bromine and an iron catalyst?
Please help
Please help
Answers
Answered by
DrBob222
Write the equation.
Convert 1.5 g toluene to moles. # moles = g/molar mass.
Using the coefficients in the balanced equation, convert moles toluene to moles of the bromotoluene.
Convert moles bromotoluene to grams. # g = moles x molar mass.
Post your work if you get stuck.
Convert 1.5 g toluene to moles. # moles = g/molar mass.
Using the coefficients in the balanced equation, convert moles toluene to moles of the bromotoluene.
Convert moles bromotoluene to grams. # g = moles x molar mass.
Post your work if you get stuck.
Answered by
GK
The reaction is:
C7H8 + Br2 --> C7H7Br + HBr
Find the molar masses of C7H8 and of C7H7Br
The theoretical yield is:
(1.5g C7H8)(mol.mass C7H7Br / mol.mass C7H8)
Answered by
Carrie
I don't understand the part where you convert moles toluene to moles of the bromotoluene.
Answered by
DrBob222
Use the equation GK wrote for you.
1 mole C7H8 give you 1 mole C7H7Br, so
moles C7H7Br = moles toluene x (1 mole C7H7Br/1 mole toluene) = moles C7H7Br.
1 mole C7H8 give you 1 mole C7H7Br, so
moles C7H7Br = moles toluene x (1 mole C7H7Br/1 mole toluene) = moles C7H7Br.
Answered by
Carrie
# moles of C7H8= .01628
.01628 mol of toluene*(1 mol C7H7Br/1 mole toluene)=.01628 mol C7H7Br
?????
.01628 mol of toluene*(1 mol C7H7Br/1 mole toluene)=.01628 mol C7H7Br
?????
Answered by
DrBob222
That's right. Since the ratio of C7H8 to moles C7H7Br is 1:1, then the moles of one equal moles of the other.
But you will see that the units of C7H8 cancel(which is what you want) and leaves the answer in units of moles C7H7Br (which is what you want). I'm sure you have seen this done in your classroom. This is dimensional analysis.
But you will see that the units of C7H8 cancel(which is what you want) and leaves the answer in units of moles C7H7Br (which is what you want). I'm sure you have seen this done in your classroom. This is dimensional analysis.
Answered by
Carrie
I got 100% yield percent
It doesn't sound right
It doesn't sound right
Answered by
DrBob222
I think you are confused. The problem, as you posted it, is to determine the theoretical yield starting with a 1.5 g sample. So the problem wants to know, in grams, how much of the C7H7Br is formed IF it is 100% yield. Give me a few minutes and I'll work the problem and see how much you should have. In the meantime, post how much you have and we can compare numbers.
Answered by
DrBob222
Check my work. I obtained 2.79 g if I didn't make an arithmetic error.
Answered by
DrBob222
moles C7H8 = 1.5/92 = 0.0163
moles C7H7Br = 0.0163 x (1 mole C7H7Br/1 mole C7H8) = 0.0163 x (1/1) = 0.0163 moles C7H7Br.
grams C7H7Br = moles x molar mass = 0.0163 x 171.04 = 2.79 g C7H7Br and I would round that to 2.8 g to agree with the number of significant figures in the 1.5. I hope you understand what I've done.
moles C7H7Br = 0.0163 x (1 mole C7H7Br/1 mole C7H8) = 0.0163 x (1/1) = 0.0163 moles C7H7Br.
grams C7H7Br = moles x molar mass = 0.0163 x 171.04 = 2.79 g C7H7Br and I would round that to 2.8 g to agree with the number of significant figures in the 1.5. I hope you understand what I've done.
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