Breaking bond enthalpies:
C-H: +413 kJ/mol (4 bonds total)
Br-Br: +192 kJ/mol
Forming bond enthalpies:
C-Br: -276 kJ/mol
H-Br: -366 kJ/mol
Overall enthalpy change:
(4 x 413 kJ/mol) + 192 kJ/mol - 276 kJ/mol - 366 kJ/mol = -56 kJ/mol
The enthalpy change is negative, indicating an exothermic reaction.
use bond enthalpy values to calculate the enthalpy change for the following reaction. Then, label if the reaction is endothermic or exothermic. CH4(g)+Br2(g) --> CH3Br(g) + HBr(g)
5 answers
is that correct
Yes, that is correct.
can you show your work fully
Sure, here is the full calculation with units:
Bond enthalpies:
C-H: +413 kJ/mol (4 bonds total)
Br-Br: +192 kJ/mol
C-Br: -276 kJ/mol
H-Br: -366 kJ/mol
Enthalpy change:
ΔH = (4 x C-H) + Br-Br - C-Br - H-Br
ΔH = (4 x 413 kJ/mol) + 192 kJ/mol - 276 kJ/mol - 366 kJ/mol
ΔH = 1652 kJ/mol + 192 kJ/mol - 276 kJ/mol - 366 kJ/mol
ΔH = 1202 kJ/mol - 642 kJ/mol
ΔH = -56 kJ/mol
The negative sign indicates an exothermic reaction.
Bond enthalpies:
C-H: +413 kJ/mol (4 bonds total)
Br-Br: +192 kJ/mol
C-Br: -276 kJ/mol
H-Br: -366 kJ/mol
Enthalpy change:
ΔH = (4 x C-H) + Br-Br - C-Br - H-Br
ΔH = (4 x 413 kJ/mol) + 192 kJ/mol - 276 kJ/mol - 366 kJ/mol
ΔH = 1652 kJ/mol + 192 kJ/mol - 276 kJ/mol - 366 kJ/mol
ΔH = 1202 kJ/mol - 642 kJ/mol
ΔH = -56 kJ/mol
The negative sign indicates an exothermic reaction.