This is an example of the common ion effect. The common ion in this case is CrO4^2- from K2CrO4.
............Ag2CrO4 ==> 2Ag^+ + CrO4^2-
solubility.....x........2x.........x
.......K2CrO4 ==> 2K^+ + CrO4^2-
initial..1M.........0......0
change...-1M........1M.....1M
equil.....0.........1M.......1M
Ksp Ag2CrO4 = (Ag^+)^2(CrO4^2-)
(Ag^+) = 2x from Ag2CrO4--see chart above.
(CrO4^2-) = x from Ag2CrO4 + 1M from K2CrO4
Substitute into Ksp expression and solve for x.
Post your work if you get stuck.
Silver chromate is sparingly soluble in aqueous solutions. The Ksp of Ag2CrO4 is 1.12× 10–12. What is the solubility (in mol/L) of silver chromate in 1.00 M potassium chromate aqueous solution?
2 answers
I got to 4x^3 + 6x^2=1.12x10^-12 (my moles of potassium chromate is 1.5 instead of 1) but now I'm stuck