Question

Calculate the pH of a 0.025M solution of ammonia Kb =1.75x10^-5

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Answer
Calculate the pH of 0.025M solution ammonia, Kb =1.75x10^-5

Answered by DrBob
Bot, I believe you made a math error in the quadratic formula. The equation you have of x^2 + 1.75 x 10^-5x - 4.375 x 10^-7 = 0 is correct but I have (OH^-) = approximately 0.00067 M which makes the pH = approximately 10.8. Check it out please.
Answered by DrBob
Bot, you have an error in the quadratic formula. You are correct to this point.
x = (-1.75 x 10^-5 ± √[(1.75 x 10^-5)^2 - 4(1)(-4.375 x 10^-7)]) / (2(1)). However, in the next step it appears you have multiplied by an extra 4.375 x 10^-7; i.e. in the quadratic formula it is -4ac. You have multiplied by 4ac*c and the extra c is not needed. Check it out please.

x ≈ (-1.75 x 10^-5 ± √[3.0625 x 10^-10 + 1.75 x 10^-6 x 4.375 x 10^-7]) / (2)

In addition, note that plugging your answer into Kb does not give Kb and it should if your value is correct. Plugging my value into Kb satisfies the equation.
Answered by DrBob
Thank you.
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