Asked by Megan
                solid (NH4)2CO3 is placed in an evacuated container at 115C. When equilibrium is reached the total pressure inside the vessel is 0.473 atm. Some solid remain in the vessel at equilibrium. Calculate Kp.
            
            
        Answers
                    Answered by
            DrBob222
            
    ..........(NH4)2CO3 ==> 2NH3 + CO2 + H2O
I..........solid.........0......0.....0
C..........solid........2p......p.....p
E..........solid........2p......p.....p
Kp = p^2NH3 * pCO2 * pH2O
Ptotal = pNH3 + pCO2 + pH2O
0.473 = 2p + p + p = 4p
Solve for p and substitute into Kp expression and solve for Kp.
    
I..........solid.........0......0.....0
C..........solid........2p......p.....p
E..........solid........2p......p.....p
Kp = p^2NH3 * pCO2 * pH2O
Ptotal = pNH3 + pCO2 + pH2O
0.473 = 2p + p + p = 4p
Solve for p and substitute into Kp expression and solve for Kp.
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