Asked by Kim
What is the boiling point of a solution of 0.515 grams of acenaphthene (C12H10) in 15 grams chloroform (CHCl3) given pure chloroform has a b.p. of 61.7 C and a Kbp of +3.63 C.
Thanks!
Thanks!
Answers
Answered by
DrBob222
mols C12H10 = grams/molar mass.
Solve for mols.
m = molality = mols/kg solvent.
Solve for m
delta T = Kb*m
Solve for delta T.
Add delta T to the normal boiling point to find the new boiling point.
Solve for mols.
m = molality = mols/kg solvent.
Solve for m
delta T = Kb*m
Solve for delta T.
Add delta T to the normal boiling point to find the new boiling point.
Answered by
Kim
Molar mass of C12H10 is 154.2078 g/mols
C12H10 = .003 mols
.2 molal
delta T = 123. 4 C
C12H10 = .003 mols
.2 molal
delta T = 123. 4 C
Answered by
DrBob222
nope. I didn't work it through but that's way too large an amount.
If I divide 0.515/154 = about 0.00334 and that divided by 0.015 = about 0.223.
I don't know why you threw two perfectly numbers away (the 23 of the 0.223) but that's in the ball park. So your mistake must be in the next to last step.
delta T = Kb*m
If I divide 0.515/154 = about 0.00334 and that divided by 0.015 = about 0.223.
I don't know why you threw two perfectly numbers away (the 23 of the 0.223) but that's in the ball park. So your mistake must be in the next to last step.
delta T = Kb*m
Answered by
Kim
Is this right?
Delta T= (3.63C)(.223)= .809 C
Delta T= (3.63C)(.223)= .809 C
Answered by
DrBob222
Yes. Now to find the new boiling point just add delta T to the normal boiling point given in the problem.
Answered by
Kim
Thank you so much for your help! :)
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