The most effective way to separate a solid substance that has dissolved in water is to boil the water away, leaving the substance behind in the beaker. This method works because it takes advantage of the difference in boiling points between the solvent (water) and the dissolved solid. Once the water evaporates, the solid will remain in the beaker.
The first option, filtering, would not separate a dissolved substance, as dissolved solids pass through the filter along with the water. The second option, pouring along a rough surface, also would not effectively capture a dissolved solid. Thus, boiling the water is the best choice in this scenario.