The statement that best explains why a rubber band analogy is not a perfect comparison for bonds in a substance when considering phase changes is:
For a phase change from solid to liquid, the bonds do not break completely and particles can still slide past each other.
This statement highlights that in a solid-to-liquid phase change (melting), the bonds do not completely break as they would in a rubber band analogy, and the particles are able to move more freely relative to each other, which is a key aspect of how liquids behave compared to solids.