To determine which of the given numbers is irrational, let's analyze each one:
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√25 - The square root of 25 is 5, which is a rational number because it can be expressed as a fraction (5/1).
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π - Pi (π) is an irrational number. It cannot be expressed as a simple fraction, and its decimal representation goes on forever without repeating.
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0 over 27 - This expression represents the number 0, which is a rational number. It can be expressed as 0/1 or any equivalent fraction.
Among the options given, the only irrational number is π.