The most accurate comparison between Tokyo and Rio de Janeiro from the given options is:
Tokyo is wealthier and larger than Rio de Janeiro; many in the suburbs have good jobs in the central city.
This statement reflects the significant differences in economic status, urban size, and job availability between the two cities. Tokyo is one of the largest and wealthiest cities in the world, with a robust economy and job market, whereas Rio de Janeiro, while it is an important tourist city, faces economic challenges and higher levels of poverty.