Nozomi constructed a copy of line segment \( \overline{AB} \) from point \( B \) to point \( C \), making \( \overline{BC} \) equal in length to \( \overline{AB} \). Therefore, since the measure of \( \overline{AB} \) is 22.3 millimeters, the measure of \( \overline{BC} \) is also 22.3 millimeters.
To find the total length of \( \overline{AC} \), we can add the lengths of \( \overline{AB} \) and \( \overline{BC} \):
\[ AC = AB + BC = 22.3 \text{ mm} + 22.3 \text{ mm} = 44.6 \text{ mm} \]
Thus, the measure of \( \overline{AC} \) is 44.6 millimeters.