Since segment AD bisects angle \( \angle CAB \), we can express \( \angle CAB \) as:
\[ \angle CAB = \angle BAD + \angle DAC \]
Since \( AD \) is a bisector, we know that:
\[ \angle BAD = \angle DAC \]
If \( \angle BAD \) measures 21 degrees, then:
\[ \angle DAC = 21 , \text{degrees} \]
Therefore:
\[ \angle CAB = \angle BAD + \angle DAC = 21 + 21 = 42 , \text{degrees} \]
Thus, the measure of \( \angle CAB \) is:
\[ \boxed{42} \] degrees.