To balance the reaction of zinc (II) hydroxide with phosphoric acid, we start with the unbalanced equation:
\[ \text{Zn(OH)}_2 + \text{H}_3\text{PO}_4 \rightarrow \text{Zn}_3(\text{PO}_4)_2 + \text{H}_2\text{O} \]
First, let's identify how many of each type of atom we have on both sides:
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On the left:
- Zinc (Zn): 1 (from Zn(OH)₂)
- Oxygen (O): 2 (from Zn(OH)₂) + 4 (from H₃PO₄) = 6
- Hydrogen (H): 2 (from Zn(OH)₂) + 3 (from H₃PO₄) = 5
- Phosphorus (P): 1 (from H₃PO₄)
-
On the right:
- Zinc (Zn): 3 (from Zn₃(PO₄)₂)
- Oxygen (O): 8 (from Zn₃(PO₄)₂) + 1 (from H₂O) = 9
- Hydrogen (H): 2 (from H₂O)
- Phosphorus (P): 2 (from Zn₃(PO₄)₂)
To balance the equation, we can adjust the coefficients. Here are the steps:
- Balance zinc (Zn): Since there are 3 Zn on the product side, place a coefficient of 3 in front of Zn(OH)₂.
- Balance phosphorus (P): There are 2 phosphate ions (PO₄³⁻) in zinc (II) phosphate, so we need to have 2 H₃PO₄. Place a coefficient of 2 in front of H₃PO₄.
- Balance water (H₂O): After adding those coefficients, count the remaining hydrogen atoms and make sure the resulting water molecules balance.
The balanced equation is:
\[ 3 \text{Zn(OH)}_2 + 2 \text{H}_3\text{PO}_4 \rightarrow \text{Zn}_3(\text{PO}_4)_2 + 6 \text{H}_2\text{O} \]
So the complete balanced chemical equation is:
\[ \boxed{3} \text{Zn(OH)}_2 + \boxed{2} \text{H}_3\text{PO}_4 \rightarrow \text{Zn}_3(\text{PO}_4)_2 + \boxed{6} \text{H}_2\text{O} \]
Thus, the molar coefficients are 3, 2, 1, and 6 for Zn(OH)₂, H₃PO₄, Zn₃(PO₄)₂, and H₂O respectively.