To determine which ordered pair is part of the solution set for the equation \( y = 4x + 2 \), we can substitute \( x = 3 \) into the equation and calculate the corresponding value of \( y \).
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Substitute \( x = 3 \) into the equation: \[ y = 4(3) + 2 \]
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Calculate: \[ y = 12 + 2 = 14 \]
The calculated value of \( y \) when \( x = 3 \) is \( 14 \). Therefore, the ordered pair \( (3, 14) \) is part of the solution set.
So the correct option is: B. (3, 14).