Given the information provided, if a student's unknown is a white solid with a density calculated to be about 1.7 g/mL, it is most likely D. phosphoric acid.
This is because phosphoric acid has a density of 1.685 g/mL and can appear as a white solid or a colorless liquid, fitting the description of the unknown substance. Sodium hydroxide, while also a white solid, has a significantly higher density of 2.13 g/mL, which does not match the student's density measurement.