If the student's unknown substance is a white solid with a density of about 1.7 g/mL, it is most likely D. phosphoric acid.
Here's the reasoning:
- Water is a colorless liquid with a density of 1.0 g/mL.
- Ethanol is also a colorless liquid with a density of 0.789 g/mL.
- Sodium hydroxide is a white solid but has a much higher density of 2.13 g/mL.
- Phosphoric acid can be a white solid or a colorless liquid and has a density of 1.685 g/mL, which is closest to the student's calculated density of about 1.7 g/mL.
Therefore, given the properties, the answer is D. phosphoric acid.