If the student's unknown is a white solid with a density calculated to be about 1.7 g/mL, it is most likely D. phosphoric acid.
This is because phosphoric acid has a density of 1.685 g/mL and can appear as a white solid, whereas sodium hydroxide, while it is also a white solid, has a density of 2.13 g/mL, which does not match the student's measurement.