The measurement that will require the use of irrational numbers is:
the diagonal of one of the cube’s faces.
To find the diagonal \( d \) of a face of the cube, you would use the formula:
\[ d = a\sqrt{2} \]
where \( a \) is the edge length of the cube. Since the edge length \( a \) is rational, \( \sqrt{2} \) is an irrational number, making \( d \) an irrational measurement.