Phosphorus pentachloride decomposes according to the chemical equation

PCl5(g) -----> PCl3 (g)+ Cl2(g)
Kc= 1.80 at 250 degrees C

A 0.206 mol sample of PCl5(g) is injected into an empty 3.30 L reaction vessel held at 250 °C. Calculate the concentrations of PCl5(g) and PCl3(g) at equilibrium.

User Icon for Katherine Katherine answered
11 years ago

I don't know what to do after I set up the Kc equation. How do you isolate x from 1.80=(x^2)/(.062-x)

User Icon for DrBob222 DrBob222 answered
11 years ago

First, I would check that 0.206/3.30. You shouldn't drop that last number; you are allowed three significant figures in 0.206 and 3.30 and that means you can have three s.f. in the answer. I have 0.0624. Second, your chemistry is right; you've done the hard part. Now it's just algebra. Here is what you start with.

(x^2)
--------- = 1.80
0.0624-x

Multiply both sides by 0.0624-x like this.
(0.0624-x)(x^2)
---------------- = 1.80*(0.0624-x)
(0.0624-x)

You see (0.0624-x) term on the left cancels since it is in the numerator and denominator and you are left with
x^2 = 1.80(0.0624-x)
Note: You could have done the same thing by cross multiplying but I don't know that you've seen that way.
Now multiply the right side to remove the parentheses, move all the terms to the left and you are left with a quadratic which you can solve for x. Let me know if you get stuck. Thanks for showing your work.

User Icon for Katherine Katherine answered
11 years ago

I was able to figure it out! Thank you very much for your help(:

User Icon for Explain Bot Explain Bot answered
11 months ago

To calculate the concentrations of PCl5(g) and PCl3(g) at equilibrium, we can use the equilibrium constant expression and the given information.

Let's assign variables to the concentrations:
Let [PCl5] represent the equilibrium concentration of PCl5(g),
Let [PCl3] represent the equilibrium concentration of PCl3(g),
And let [Cl2] represent the equilibrium concentration of Cl2(g).

According to the balanced chemical equation:
PCl5(g) -----> PCl3(g) + Cl2(g)

The stoichiometry is 1:1:1, meaning:
For every 1 mole of PCl5 that decomposes, 1 mole of PCl3 and 1 mole of Cl2 are formed.

Given that the initial amount of PCl5(g) is 0.206 mol and the reaction vessel has a volume of 3.30 L, we can determine the initial concentration of PCl5(g):

[PCl5] = (0.206 mol) / (3.30 L) = 0.0624 M

Let's assume the change in concentration of PCl5(g) at equilibrium is -x, as it is being consumed. The change in concentration of PCl3(g) and Cl2(g) will also be +x, as they are being formed.

At equilibrium, the concentrations will be:
[PCl5] = 0.0624 - x (M)
[PCl3] = x (M)
[Cl2] = x (M)

We can now write the expression for the equilibrium constant (Kc) in terms of concentrations:

Kc = ([PCl3] * [Cl2]) / [PCl5]

Substituting the known values:
1.80 = (x * x) / (0.0624 - x)

Simplifying the equation:
1.80 * (0.0624 - x) = x^2

Expanding:
0.11232 - 1.80x = x^2

Rearranging the equation to set it equal to zero:
x^2 + 1.80x - 0.11232 = 0

Now, we can solve this quadratic equation for x using the quadratic formula:

x = (-b ± √(b^2 - 4ac)) / (2a)

a = 1, b = 1.80, c = -0.11232

Calculating the discriminant:
D = b^2 - 4ac
D = (1.80)^2 - 4(1)(-0.11232)

D = 3.24 + 0.44864
D = 3.68864

Since the discriminant is positive, we have two solutions for x.

Using the quadratic formula:
x = (-1.80 ± √(3.68864)) / 2

Calculating x:
x₁ = (-1.80 + √(3.68864)) / 2
x₁ = (-1.80 + 1.92125) / 2
x₁ = 0.12125 / 2
x₁ = 0.060625

x₂ = (-1.80 - √(3.68864)) / 2
x₂ = (-1.80 - 1.92125) / 2
x₂ = -3.72125 / 2
x₂ = -1.860625

Since negative concentrations are not physically meaningful, we can discard the negative value. So, x = 0.060625 M.

Now, we can calculate the equilibrium concentrations:
[PCl5] = 0.0624 - x
[PCl5] = 0.0624 - 0.060625
[PCl5] = 0.001775 M

[PCl3] = x
[PCl3] = 0.060625 M

[Cl2] = x
[Cl2] = 0.060625 M

Therefore, at equilibrium:
[PCl5] = 0.001775 M
[PCl3] = 0.060625 M
[Cl2] = 0.060625 M