Asked by RZeal

3HClO2(aq) +2Cr3+(aq) + 4H2O(l) -> 3HClO(aq) + (Cr2O7)2–(aq) + 8H+(aq)

At pH 0.00, with [Cr2O72–] = 0.80 M, [HClO2] = 0.15 M, and [HClO] = 0.20 M, the cell voltage is found to be 0.15 V. Calculate the concentration of [Cr3+] in the cell

Ecell = 0.31

Not sure how to really work this one out, more complicated than other problems like this

Answers

Answered by DrBob222
You have conflicting information. The problem says cell voltage is 0.15 v and you say Ecell = 0.31. I suspect one of those numbers is Eocell. If that is the case, then
Ecell = Eocell -(0.05916/6)*log Q and log Q (HClO)^3*(Cr2O7^2-)*(1)^8/(HClO2)^3*(Cr^3+)^2
The easy to is to solve for log Q, then Q, then solve for Cr^3+
Answered by RZeal
Sorry about the confusion
Ecell = 0.15 and Eocell = 0.31
Answered by DrBob222
Just plug the numbers into my equation above and solve for [Cr^3+]
Answered by RZeal
Thanks I was able to solve it!
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