At 22 °C an excess amount of a generic metal hydroxide M(OH)2, is mixed with pure water. The resulting equilibrium solution has a pH of 10.56. What is the Ksp of the compound at 22 °C?

I have found my [OH-] concentration (3.63x10^-4) but I'm not sure I'm setting up my ICE table or my Ksp expression right:

M(OH)2 ---> M^2+ + 2OH^-
---------------------------------
excess 0 2(3.63x10^-4)
+x +x
----------------------------------
less x (7.26x10^-4)x

Ksp = [M][OH^-]^2

=(x)(7.26x10^-4x +x)

Not real sure where to go from here...
Thank you for any guidance!

User Icon for DrBob222 DrBob222 answered
12 years ago

Your 3.63E-4 = (OH^-) is correct but your ICE table needs some work.

..........M(OH)2 ==> M^2+ + 2OH^-
equil.......................3.63E-4
[note: If the pH is 10.58 and OH^- = 3.63E-4, then that's what OH IS. It isn't 2 times that. So
Ksp =- (M^2+)(OH^-)^2
(M^2+) = 1/2 x 3.63E-4 = 1.82E-4
(OH^-) = 3.63E-4
Substitute into Ksp expression and solve for Ksp.

User Icon for Miaow Miaow answered
12 years ago

Oh geez, thank you SO much! And so quick!

User Icon for jen jen answered
12 years ago

How did you find the concentration of [OH-]

User Icon for vox vox answered
11 years ago

14-pH = pOH

From the pOH, you can calculate [OH-] raising 10 to the opposite pOH power.

[OH-]=10^(-pOH)

User Icon for hey hey answered
4 years ago

why is OH/2 of M^2+

User Icon for Explain Bot Explain Bot answered
1 year ago

To find the Ksp of the compound, you need to use the equilibrium concentration of OH- and the stoichiometric relationship between M(OH)2 and OH- ions.

You correctly found the concentration of OH- ions, which is 3.63x10^-4 M.

Now, let's set up the ICE table correctly:

M(OH)2 <--> M^2+ + 2OH-

Initial concentration: excess 0 2(3.63x10^-4)
Change in concentration: +x +x +2x
Equilibrium concentration: excess + x x 2(3.63x10^-4) + x

Since the concentration of OH- ions is in excess, we can neglect the change in concentration of the M(OH)2 compound, so the equilibrium concentration of M(OH)2 can be approximated as "excess + x".

Now we can substitute these values into the Ksp expression:

Ksp = [M][OH-]^2
= (excess + x)(2(3.63x10^-4) + x)^2

Now, since the value of x is very small compared to the initial concentration, we can assume that the concentration of OH- ions is approximately equal to "2(3.63x10^-4) + x". This allows us to simplify the expression:

Ksp ≈ (excess + x)(2(3.63x10^-4) + x)^2
≈ (excess)(2(3.63x10^-4))^2

Since the question states that there is an "excess" of M(OH)2, we can assume that the concentration of M(OH)2 is much larger compared to the concentration of OH- ions. Therefore, we can omit the term "x" in the expression, resulting in:

Ksp ≈ (excess)(2(3.63x10^-4))^2
≈ (excess)(2(3.63x10^-4))^2
≈ (excess)*(2(3.63x10^-4))^2

Now you can calculate the Ksp by inserting the appropriate values for "excess" into the equation and performing the necessary calculations.

I hope this helps! Let me know if you have any further questions.