HIO3 + FeI2 + HCl --> FeCl3 + ICl

(in acidic solution)
Show and label the two balanced half-reactions (oxidation and reduction). Add H2Os, H+s or OH-s as needed.

User Icon for DrBob222 DrBob222 answered
14 years ago

Jillian--It won't do much good for us to balance these for you. You need to learn to do them yourself. It's a matter of following the rules. Tell us what your hang up is and let us help you through them.

User Icon for jillian jillian answered
14 years ago

I don't know which are the half reactions.

User Icon for Explain Bot Explain Bot answered
11 months ago

To balance the given redox reaction in acidic solution, we need to identify the oxidation and reduction half-reactions.

First, let's determine the oxidation numbers of the elements in the compounds involved:

HIO3: In this compound, the oxidation number of iodine (I) is +5.
FeI2: In this compound, the oxidation number of iron (Fe) is +2.
HCl: In this compound, the oxidation number of chlorine (Cl) is -1.
FeCl3: In this compound, the oxidation number of iron (Fe) is +3.
ICl: In this compound, the oxidation number of iodine (I) is +1.

From the given reaction, we can observe that iodine is reduced from an oxidation state of +5 to +1, while iron is oxidized from +2 to +3. Therefore, the reduction half-reaction involves the reduction of iodine, and the oxidation half-reaction involves the oxidation of iron.

Half-Reactions:
Reduction Half-Reaction: I2 + 10e- + 12H+ → 2ICl + 6H2O
Oxidation Half-Reaction: Fe → Fe3+ + 3e-

Now, let's balance the number of atoms and charges on each side of the half-reactions:

Reduction Half-Reaction:
I2 + 10e- + 12H+ → 2ICl (balanced on atoms and charges)

Oxidation Half-Reaction:
Fe → Fe3+ + 3e- (balanced on atoms and charges)

Next, we need to balance the number of electrons transferred in each half-reaction, so that they cancel out when combined:

Reduction Half-Reaction:
I2 + 10e- + 12H+ → 2ICl + 6H2O (multiply by 6 to balance electrons)
6I2 + 60e- + 72H+ → 12ICl + 36H2O

Oxidation Half-Reaction:
Fe → Fe3+ + 3e-

Now, we can combine the two balanced half-reactions by multiplying them accordingly:

Overall Balanced Equation:
6I2 + 60e- + 72H+ + 6Fe → 12ICl + 36H2O + 6Fe3+

Remember to double-check the balanced equation and ensure that the number of atoms and charges are balanced on both sides.