Part 1: I would choose the universe for label A because it contains everything. Label B would be for a galaxy since it's a big collection of stars, and I'd pick the solar system for label C because it has all the planets orbiting a star. Lastly, Mars fits perfect for label D because it's just one planet that we can land on.
Part 2: Hierarchical level D is different because it's just one small planet, while the others are much bigger and contain many more things. The universe, galaxy, and solar system are like big boxes, but Mars is just a toy inside one of those boxes.