To add the polynomial expressions \(2r^2 - 3r + 4\) and \(2r^2 + 3r + 6\), you simply combine like terms.
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Add the \(r^2\) terms: \[ 2r^2 + 2r^2 = 4r^2 \]
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Add the \(r\) terms: \[ -3r + 3r = 0r \]
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Add the constant terms: \[ 4 + 6 = 10 \]
Now, combine all these results: \[ 4r^2 + 0r + 10 = 4r^2 + 10 \]
Therefore, the sum of the polynomial expressions is: \[ \boxed{4r^2 + 10} \]