It made everyone born in or naturalized by the United States a full citizen. As such they cannot be slaves.
http://en.wikipedia.org/wiki/Fourteenth_Amendment_to_the_United_States_Constitution#Text
What was the significance of the first section of the 14th amendment to Reconstruction?
3 answers
but why was this significant during reconstuction?
This article explains more.
http://www.pbs.org/wnet/jimcrow/stories_events_14th.html
http://www.pbs.org/wnet/jimcrow/stories_events_14th.html