Asked by Spencer
                Calculate the concentrations of all species present in a 0.33 M solution of ethylammonium chloride (C2H5NH3Cl).
Okay so i tried doing
HA = H + A
ice table regular it doesnt work
idk what Ka to use. b/c of the chloride.
i have to find [C2H5NH2][H+][OH -][C2H5NH3+][Cl -]
            
        Okay so i tried doing
HA = H + A
ice table regular it doesnt work
idk what Ka to use. b/c of the chloride.
i have to find [C2H5NH2][H+][OH -][C2H5NH3+][Cl -]
Answers
                    Answered by
            DrBob222
            
    This is a salt so it dissolves (and hydrolyzes in H2O).
C2H5HN3Cl(aq)==> C2H4NH3^+ + Cl^-
That gives you the Cl^- immediately. It's 0.33 M.
Now the salt dissolves in water (use NH4^+ as an example).
C2H5NH3^ + HOH ==> C2H4NH2 + H3O^+
Does that help? Use Ka = Kw/Kb and Kb is for C2H4NH2 (ethylamine).
    
C2H5HN3Cl(aq)==> C2H4NH3^+ + Cl^-
That gives you the Cl^- immediately. It's 0.33 M.
Now the salt dissolves in water (use NH4^+ as an example).
C2H5NH3^ + HOH ==> C2H4NH2 + H3O^+
Does that help? Use Ka = Kw/Kb and Kb is for C2H4NH2 (ethylamine).
                    Answered by
            Spencer
            
    no because i keep getting .01359 for C2H4NH3^+
but obviously that's wrong
i did x^2/.33-x=5.6e-4
    
but obviously that's wrong
i did x^2/.33-x=5.6e-4
                    Answered by
            DrBob222
            
    No, I think if you will read my former response closely that isn't what I said to do.
C2H5NH3^+ + HOH ==> C2H5NH2 + H3O^+
Ka = Kw/Kb = (C2H5NH2)(H3O^+)/(C2H5NH3^+)
Now plug in Kw for water, Kb for ethylamine, 0.33 for the salt and calculate the y and y in the numerator. I get approximately 3 x 10^-6 M for H3O^+ so it should be close to that. I don't know what your value is for Kb but I looked up ethylamine on the internet and found 4.7 x 10^-4. Obviously you should use your book's value.
    
C2H5NH3^+ + HOH ==> C2H5NH2 + H3O^+
Ka = Kw/Kb = (C2H5NH2)(H3O^+)/(C2H5NH3^+)
Now plug in Kw for water, Kb for ethylamine, 0.33 for the salt and calculate the y and y in the numerator. I get approximately 3 x 10^-6 M for H3O^+ so it should be close to that. I don't know what your value is for Kb but I looked up ethylamine on the internet and found 4.7 x 10^-4. Obviously you should use your book's value.
                    Answered by
            Spencer
            
    I don't understand why u did the Ka=Kw/Kb
why cant u just use Kb? isnt it a base?
    
why cant u just use Kb? isnt it a base?
                    Answered by
            DrBob222
            
    C2H5NH2 is a base but you don't have the base. You have the salt, C2H5NH3Cl which contains the conjugate acid of the base or C2H5NH3^+. It's the acid that is hydrolyzing (reacting) with the water to give the base. You can look up Kb but no tables (at least none I know of) are around for the Ka. So we calculate Ka by Kw/Kb since we CAN look up Kb for C2H5NH2
    
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