Asked by Robby

H2 (g)+I2 (g)↔2HI(g)

Calculate ΔG for the system at 700 K when the concentrations are [H2] = 0.12M, [I2] = 0.27M, and [HI] = 0.118M.

What would be my first step? If I make an ICE chart, what would I do from there? I just need the first step to help me out :(
THANKS!

Answers

Answered by DrBob222
I assume this is not at equilibrium. If that is the case, then
dG = dGorxn + RTlnQ
dGorxn you obtain from
dGorxn = *n*dGo formation products) - (n*dGo formation reactants)

Then Q is (HI)^2/(H2)(I2)
Answered by Robby
Dr. Bob, as grateful as I am you took the time to answer my question, I do not believe you are right. In order to get Q, it needs to be in atm, and I am dealing with M?

if I am wrong, can you explain to me what I would need to do next?
Answered by DrBob222
Why must you use atm? You use atm for gases and when you have pressures, these aren't gases so you use molarity. Calculation of Q occurs for either. In fact, one may use, if the situation occurs, a mix where pressure is used for the gas ad molarities for the solutions. For example,
Zn(s) + 2H^+(aq) ==> Zn^2+(aq) + H2(g)
Q for that rxn is (Zn^2+)*pH2/(H^+)^2
The Zn^2+ and H^+ are substituted in M and pH2 in atm.
However, if you feel uncomfortable with this, please do seek a second opinion.

To proceed with the problem, first calculate dGorxn from the equation I provided above, substitute the concns and calculate Q, then plug that into the dGrxn = dGo + RTlnQ and solve for dGrxn Good luck.
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