Question

The equilibrium constant, Kp, equals 3.40 for the isomerization reaction:
cis-2-butene trans-2-butene.
If a flask initially contains 0.250 atm of cis-2-butene and 0.145 atm of trans-2-butene, what is the equilibrium pressure of each gas?

Answer 1

.....cis-butene==> trans-butene
I......0.250........0.145
C.......-x...........+x
E......0.250-x.....0.145+x

Substitute the E line into Kp expression and solve for x, 0.250-x and 0.145+x.

How did I know to make the C line -x......+x an not +x......-x; i.e., how do I know it will shift from cis to trans and NOT trans to cis.
I calculated Qp = 0.145/0.250 = 0.58 and compared that value with Kp. It is smaller than Kp and that tells me the numerator is too small and the denominator is too large so I know the reaction must shift to the right to form more trans. "-)

Answer 2

.0898 .305

Answer 3

You must solve for Q first to see which way the reaction proceeds.