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Mendi
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The correction terms in the Van der Waals equation for a gas are designed to correct
A. the pressure term (P +a/V2) for the
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I think that your concentrations of Pb and Cl are lower than you think they are. If you were to add 1L of 1M Pb+ to 1L of 1M Cl-, remember that you now have doubled the amount of liquid. You now have 2 L of liquid with 1 mole of Pb+ and 1 mole of Cl- in
