With a relative standard deviation of 32.51+_ 0.15. Cant the result of 32.14 and 32.75 be discarded because they are out of the .15 range?

Answer 1

My usual answer is that results may be discarded if
a. the analyst made an error during the procedure or
b. the result is outside the limits of the t test or the Q test (or some other viable test).