The best response to explain why there is less biomass at the top of the energy pyramid is:
Secondary and tertiary consumers have to consume a lot more food to support themselves, so there are fewer of them.
This is because energy transfer in an ecosystem is inefficient, with only about 10% of the energy from one trophic level being available to the next. As a result, fewer organisms can be supported at the higher levels of the pyramid, leading to lower biomass in those tiers.