why do more electrons increase dispersion forces?
3 answers
More electrons usually means a larger size and that means higher dispersion forces in general.
why? or maybe the right question is how does the size contribut to the forces?
The larger an atom the farther the electrons are away from the nucleus; therefore, the easier it is to distort them. Here is a site that talks about that.
http://www.chem.purdue.edu/gchelp/liquids/disperse.html
http://www.chem.purdue.edu/gchelp/liquids/disperse.html