The correct answer is:
A. They flow passively from high to low concentration via facilitated diffusion as they flow through ATP synthase the enzyme spins and produces ATP.
In the process of photosynthesis, specifically during the light-dependent reactions, hydrogen ions (protons) accumulate in the thylakoid space, creating a proton gradient. As protons flow back into the stroma through ATP synthase, they do so passively due to this gradient, and their movement drives the synthesis of ATP from ADP and inorganic phosphate.