The correct statement is:
Iodine will indicate starch in a substance.
Iodine turns blue-black in the presence of starch.
The other statements are incorrect:
- Vinegar does not specifically indicate sugar; it is an acid, and while it may affect sugar solutions, it does not indicate their presence.
- Benedict's test is used to detect reducing sugars, not starch.
Therefore, the correct pairing is the first one.