The situation that most effectively illustrates an instance of Newton's first law of motion is:
A car's passenger moves in the forward direction when the car comes to an abrupt stop.
Newton's first law, often called the law of inertia, states that an object in motion will remain in motion at a constant velocity unless acted upon by a net external force. When the car stops suddenly, the passenger continues to move forward due to inertia until a force (like the seatbelt or the dashboard) acts on them to stop their motion.