The property that can be used to expand the expression \( 5(3x - 67) \) is the Distributive Property.
This property states that \( a(b + c) = ab + ac \) and can also be applied to subtraction. In this case, it would be utilized to distribute the 5 across the terms inside the parentheses:
\[ 5(3x - 67) = 5 \cdot 3x - 5 \cdot 67 \]
So, the correct response is Distributive Property.