The most fitting description of God's actions in this context would be "justly." This term reflects the idea that God's response to Adam and Eve's disobedience and the subsequent atonement through Jesus was based on divine justice and righteousness rather than negative emotions like begrudgingly or angrily.
When God punished Adam and Eve and accepted Jesus’ sacrifice as atonement for sin, God acted
begrudingly
reluctantly
favorably
impulsively
justly
angrily
prejudicially
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