When an ionic compound such as sodium chloride (NaCl) is placed in water, the component atoms of the NaCl crystal dissociate into individual sodium ions (Na+) and chloride ions (Cl-). In contrast, the atoms of covalently bonded molecules (e.g., glucose, sucrose, glycerol) do not generally dissociate when placed in aqueous solution. Which of the following solutions would be expected to contain the greatest number of solute particles (molecules or ions)?

1 liter of 1.0 M glucose
1 liter of 0.5 M NaCl
1 liter of 1.0 M NaCl
1 liter of 1.0 M NaCl and 1 liter of 1.0 M glucose will contain equal numbers of solute particles.

1 answer

To determine which of the solutions contains the greatest number of solute particles (molecules or ions), we need to consider how many particles are produced when each substance dissolves in water.

  1. 1 liter of 1.0 M glucose: Glucose is a covalent compound and does not dissociate in solution. Therefore, 1.0 M glucose provides 1.0 moles of glucose molecules per liter.

    • Total particles = 1.0 M × 1 L = 1.0 moles of glucose molecules.
  2. 1 liter of 0.5 M NaCl: Sodium chloride (NaCl) dissociates completely in water into two ions: Na⁺ and Cl⁻. Therefore, 0.5 M NaCl will yield 0.5 moles of Na⁺ and 0.5 moles of Cl⁻.

    • Total particles = (0.5 M NaCl × 1 L) × 2 (due to dissociation) = 0.5 moles × 2 = 1.0 moles of ions.
  3. 1 liter of 1.0 M NaCl: Similarly, 1.0 M NaCl will dissociate into Na⁺ and Cl⁻ ions.

    • Total particles = (1.0 M NaCl × 1 L) × 2 = 1.0 moles × 2 = 2.0 moles of ions.
  4. 1 liter of 1.0 M NaCl and 1 liter of 1.0 M glucose: Here, we have both glucose (1.0 M) and NaCl (1.0 M). The contributions would be:

    • From glucose: 1.0 moles of glucose.
    • From NaCl: (1.0 M NaCl × 1 L) × 2 = 2.0 moles of ions.
    • Total = 1.0 moles (glucose) + 2.0 moles (NaCl) = 3.0 moles of particles.

Now, let's summarize the total number of solute particles for each option:

  • 1 liter of 1.0 M glucose: 1.0 moles
  • 1 liter of 0.5 M NaCl: 1.0 moles
  • 1 liter of 1.0 M NaCl: 2.0 moles
  • 1 liter of 1.0 M NaCl and 1 liter of 1.0 M glucose: 3.0 moles

The 1 liter of 1.0 M NaCl and 1 liter of 1.0 M glucose solution will contain the greatest number of solute particles with a total of 3.0 moles.