Start with the equation
Cl2 + H2 = 2HCl
so one mole of each forms 2 moles of HCl.
We know that number of moles is equivalent to volume. So 1 volume of each forms 2 volumes of HCl (equal volumes of gases contain the same number of moles under the same conditions).
When a volume of H2 reacts with an equal volume of Cl2 (assume you have 1 L of each) at the same temperature and pressure, what volume of product having the formula HCl is formed?
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