What volume of oxygen at stp is produced on heating 42.02 g of potassium trioxochlo rate v

1 answer

To determine the volume of oxygen produced, we need to use the molar ratio between potassium trioxochlorate(V) and oxygen.

First, let's calculate the moles of potassium trioxochlorate(V) using its molar mass:

Molar mass of potassium trioxochlorate(V) (KClO₃) = 122.55 g/mol

Moles of KClO₃ = mass of KClO₃ / molar mass of KClO₃
= 42.02 g / 122.55 g/mol
= 0.342 moles

According to the balanced chemical equation for the decomposition of KClO₃:

2 KClO₃ → 2 KCl + 3 O₂

The molar ratio between KClO₃ and O₂ is 3:1. Therefore, for every 2 moles of KClO₃, 3 moles of O₂ are produced.

Moles of O₂ produced = (3 moles O₂ / 2 moles KClO₃) x 0.342 moles KClO₃
= 0.513 moles

Now, we can use Avogadro's law to determine the volume of oxygen at STP (standard temperature and pressure):

1 mole of any ideal gas at STP occupies 22.4 L.

Volume of O₂ produced = moles of O₂ produced x 22.4 L/mol
= 0.513 moles x 22.4 L/mol
= 11.48 L

Therefore, the volume of oxygen produced on heating 42.02 g of potassium trioxochlorate(V) at STP is approximately 11.48 liters.