To determine when the equation \(-5 = 4 - \left( \frac{3x}{4} - 3x \right)\) is undefined, we first need to simplify the expression inside the parentheses.
The expression \(\frac{3x}{4} - 3x\) can be simplified by first rewriting \(3x\) with a common denominator:
\[ 3x = \frac{12x}{4} \]
Now substituting this back into the expression, we have:
\[ \frac{3x}{4} - 3x = \frac{3x}{4} - \frac{12x}{4} = \frac{3x - 12x}{4} = \frac{-9x}{4} \]
Thus, we can rewrite the equation as:
\[ -5 = 4 - \left( \frac{-9x}{4} \right) \]
This simplifies to:
\[ -5 = 4 + \frac{9x}{4} \]
Now, let's isolate \(\frac{9x}{4}\):
\[ -5 - 4 = \frac{9x}{4} \]
\[ -9 = \frac{9x}{4} \]
Next, we can clear the fraction by multiplying both sides by 4:
\[ -9 \cdot 4 = 9x \]
\[ -36 = 9x \]
Now, we solve for \(x\):
\[ x = \frac{-36}{9} = -4 \]
Finally, we find that the equation becomes undefined when \(x = -4\).
So, the value that makes the equation undefined is:
\[ \boxed{-4} \]