What determines the colors of the special emissions lines produced by a gas in a discharge tube

1 answer

The colors of the special emission lines produced by a gas in a discharge tube are determined by the energy levels of the atoms or ions of that particular gas. When a gas is excited by an electric field in a discharge tube, electrons are promoted to higher energy levels. As these excited electrons return to their ground state, they release energy in the form of photons. The energy difference between the excited state and the ground state determines the wavelength (color) of the emitted light.

Each element or compound has a unique set of energy levels, and therefore, emits a specific set of emission lines with distinct colors. This phenomenon is due to the quantized nature of electron energy levels in an atom or ion. The emission lines correspond to the electronic transitions between different energy levels, and these transitions are characteristic of the gas being used. By analyzing the colors of the emission lines, scientists can identify the presence of specific elements or compounds in a discharge tube.