Using the van der Waals equation, calculate the pressure (in atmospheres) exerted by 91.14 g of Cl2 at 91.11 °C in a 1.00 L container. The van der Waals constants for Cl2 are a = 6.490 L2*atm/mol2 and b = 0.05620 L/mol.

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Instead of us going through this long long calculation and you checking your work, why don't you show your work and let us check it for you.