Use the table to answer the question.

Reaction Bonds Present Energy of Bonds Broken and Formed (kJ/mol)
C + O2→CO2
O=O

2 C=O

499

1478

N2+O2→2NO
N≡N

O=O

2 N=O

946

499

1214

S+O2→SO2
O=O

2 S=O

499

1044

2CO+O2→2CO2
2 C≡O

O=O

4 C=O

2148

499

2956

Which reaction is endothermic?

(1 point)
Responses

N2+O2→2NO
N sub 2 plus O sub 2 rightarrow 2 N O

S+O2→SO2
S plus O sub 2 rightarrow S O sub 2

C + O2→CO2
C plus O sub 2 rightarrow C O sub 2

2CO+O2→2CO2

1 answer

To determine which reaction is endothermic, we need to compare the total energy required to break the bonds with the total energy released when forming the bonds.

The general formula is: Total Energy of Bonds Broken - Total Energy of Bonds Formed = Change in Energy (ΔE)

If ΔE is positive, the reaction is endothermic.

Let's analyze each reaction:

  1. C + O2 → CO2

    • Bonds broken: 1 O=O (499 kJ/mol)
    • Bonds formed: 2 C=O (2 × 799 kJ/mol = 1598 kJ/mol)
    • ΔE = 499 - 1598 = -1099 kJ/mol (exothermic)
  2. N2 + O2 → 2NO

    • Bonds broken: 1 N≡N (946 kJ/mol) + 1 O=O (499 kJ/mol) = 1445 kJ/mol
    • Bonds formed: 2 N=O (2 × 607 kJ/mol = 1214 kJ/mol)
    • ΔE = 1445 - 1214 = 231 kJ/mol (endothermic)
  3. S + O2 → SO2

    • Bonds broken: 1 O=O (499 kJ/mol)
    • Bonds formed: 2 S=O (2 × 522 kJ/mol = 1044 kJ/mol)
    • ΔE = 499 - 1044 = -545 kJ/mol (exothermic)
  4. 2CO + O2 → 2CO2

    • Bonds broken: 2 C≡O (2 × 1072 kJ/mol = 2144 kJ/mol) + 1 O=O (499 kJ/mol) = 2643 kJ/mol
    • Bonds formed: 4 C=O (4 × 799 kJ/mol = 3196 kJ/mol)
    • ΔE = 2643 - 3196 = -553 kJ/mol (exothermic)

From this analysis, the reaction that is endothermic is:

N2 + O2 → 2NO