To make the solution more orange, you would want to favor the formation of \( Cr_2O_7^{2-} \) ions, which are orange.
Looking at the reaction:
\[ Cr_2O_7^{2-} (aq) + H_2O (l) ⇄ 2 CrO_4^{2-} (aq) + 2 H^+ (aq) \]
To shift the equilibrium to the left (favoring \( Cr_2O_7^{2-} \)), you can decrease the concentration of \( CrO_4^{2-} \), which is yellow, or increase the concentration of \( H^+ \) ions (decreasing the pH).
Therefore, the most effective change to make the solution more orange would be:
Decreasing the pH.