use the information in the table to answer the question
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reaction | bonds present | energy bonds broken and formed (kJ/mol)
C+O2>CO2 | O+O | 498
2 C=O | 1478
N2+O2>2NO | N≡N | 946
O=O | 498
2 N=O | 1214
S+O2>SO2 | O=O | 498
2 S=O | 1044
2CO+O2>SO2| 2 C≡O | 2148
O=O | 498
4 C=O | 2956
which reaction is endo thermic?
A ) N2+O2>2NO
B ) S+O2>SO2
C ) 2CO+O2>2CO2
D ) C+O2>CO2
1 answer
Let's compare the energies for each reaction given in the table:
A) N2 + O2 > 2NO
Energy required to break bonds: N≡N (946 kJ/mol) + O=O (498 kJ/mol) = 1444 kJ/mol
Energy released forming new bonds: 2 N=O (2 * 607 kJ/mol) = 1214 kJ/mol
Net energy = Energy required - Energy released = 1444 - 1214 = 230 kJ/mol (positive value indicates endothermic)
B) S + O2 > SO2
Energy required to break bonds: O=O (498 kJ/mol)
Energy released forming new bonds: 2 S=O (1044 kJ/mol)
Net energy = Energy required - Energy released = 498 - 1044 = -546 kJ/mol (negative value indicates exothermic)
C) 2CO + O2 > 2CO2
Energy required to break bonds: 2 C=O (2 * 1074 kJ/mol) + O=O (498 kJ/mol) = 2646 kJ/mol
Energy released forming new bonds: 4 C=O (4 * 739 kJ/mol) = 2956 kJ/mol
Net energy = Energy required - Energy released = 2646 - 2956 = -310 kJ/mol (negative value indicates exothermic)
D) C + O2 > CO2
Energy required to break bonds: O=O (498 kJ/mol)
Energy released forming new bonds: 2 C=O (1478 kJ/mol)
Net energy = Energy required - Energy released = 498 - 1478 = -980 kJ/mol (negative value indicates exothermic)
From the calculations above, we can see that:
- Reaction A (N2 + O2 > 2NO) is the only endothermic reaction as it has a positive net energy change.
- Reactions B, C, and D are exothermic as they have negative net energy changes, meaning they release more energy than they absorb.
Therefore, the answer is:
A) N2 + O2 > 2NO