The measurement that will require the use of irrational numbers is:
the diagonal of one of the cube’s faces.
To explain: The diagonal of a face of the cube can be calculated using the Pythagorean theorem. If the edge length of the cube is \( a \), the diagonal \( d \) of a face would be calculated as \( d = \sqrt{a^2 + a^2} = \sqrt{2a^2} = a\sqrt{2} \). Since \( \sqrt{2} \) is an irrational number, this means that the diagonal will also be an irrational number if \( a \) is a rational number.