To balance the equation:
CH4 + Cl2 → CCl4 + HCl
You need to ensure that the number of atoms of each element on the reactant side (left) is equal to the number of atoms on the product side (right).
- Carbon (C): There is 1 C in CH4 and 1 C in CCl4. This is balanced.
- Hydrogen (H): There are 4 H in CH4 and 1 H in HCl. To balance the H, you need 4 HCl. So, you should put 4 in front of HCl.
- Chlorine (Cl): After balancing the H, you have 4 Cl from CCl4 and 4 Cl from 4 HCl, totaling 8 Cl. Therefore, you need 4 Cl2 on the reactant side to provide 8 Cl atoms.
So the balanced equation is:
CH4 + 4 Cl2 → CCl4 + 4 HCl
Thus, the correct numbers to balance this equation are:
4, 4.