To find the concentration of salt in each solution, we can use the formula for concentration, which is:
\[ \text{Concentration} = \frac{\text{Mass of solute (NaCl)}}{\text{Volume of solvent (water)}} \]
For each solution:
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Solution A: \[ \text{Concentration} = \frac{5.0 \text{ g}}{50.0 \text{ mL}} = 0.1 \text{ g/mL} \]
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Solution B: \[ \text{Concentration} = \frac{5.0 \text{ g}}{75.0 \text{ mL}} \approx 0.06667 \text{ g/mL} \]
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Solution C: \[ \text{Concentration} = \frac{5.0 \text{ g}}{100.0 \text{ mL}} = 0.05 \text{ g/mL} \]
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Solution D: \[ \text{Concentration} = \frac{5.0 \text{ g}}{125.0 \text{ mL}} = 0.04 \text{ g/mL} \]
Comparing the concentrations:
- Solution A: 0.1 g/mL
- Solution B: 0.06667 g/mL
- Solution C: 0.05 g/mL
- Solution D: 0.04 g/mL
Thus, Solution A has the highest concentration of salt.
So, the answer is: Solution A