The products of the reaction between zinc and sulfruric acid are zinc sulfate, hydrogen sulfide, and water. Balance the equation using the electron-transfer method

1 answer

Zn + H2SO4 ==> ZnSO4 + H2S + H2O
Zn changes from 0 on the left to +2 on the right for loss of 2e.
S changes from +6 on the left in SO4^2- to -2 on the right for gain of 8e.
(S in SO4 also is on the left and right unchanged but we take care of that later)
So we multiply Zn by 4 (to make 4 x 2 = 8e and H2SO4 by 1 (to make 1 x 8 = 8e gained) this way.
4Zn + 1H2SO4 ==> 4ZnSO4 + 1H2S + H2O
That takes care of the redox part. Zn is OK but we have added 4 SO4^2- on the right from the 4ZnSO4 so we need to add 4 more H2SO4 to balance the non-redox part this way.
4Zn + 5H2SO4 ==> 4ZnSO4 + 1H2S + H2O
Then finish balancing by inspection.
4Zn + 5H2SO4 ==> 4ZnSO4 + H2S + 4H2O
Done but note that this is not the USUAL rxn with Zn and H2SO4.